Paul, with a perfectly straight barrel, either method should theoretically get the same results as it would make no difference where you were able to indicate in the barrel whether at the muzzle, breech or the middle of the bore if you could get there. It would be running dead true no matter where you indicated. As long as the chamber is cut concentric to the bore, it shouldn't make any difference how it's done. I don't know whether you remember or have read a statement that was in Warren Page's "The Accurate Rifle" that is if I remember correctly. There were two barrels, one was crooked as a snake, the other was pretty straight. The crooked barrel shot lights out, the straight one was just so so. Of course, that was a long time ago and aggs have gotten better and better. A barrel will either shoot or it won't. But, the job of anyone chambering barrels is to have a method that takes the gunsmith out of the equation as to whether a barrel will shoot or not.
I want the throat of my barrels centered with the chamber. That's where the bullet starts, that's where I want to start the centering of the barrel in the lathe. Most barrels aren't crooked enough to make much difference. Every once in a great while you'll run across a barrel that isn't the straightest. Thankfully, they are few and far between.
Mike