I don't want to hijack the thread but.
I've tried solid carbide tools inserted into a custom steel holder and thought they sucked for barrel work.
For chambers I did, I made a specific tool for the cartridge. The were all coolant through, indexables using either 120 deg for 30 cal or 80deg for smaller. Radii were .007 and .002. All Circle Machine inserts. All the bars were one piece tool steel holders and bars together, heat treated and drawn. Started with 2" material. Profiled both front and back (as viewed via x axis). All blow chips down the barrel and make big chore-boys in the spindle bore.
For really small stuff, I used a Bokum bar (solid carbide) in a custom holder. I've done 17,22,6, 6.5 and 30. As to finishes, they seemed to work ok for me. How nice do they have to be?