http://www.ctmuzzleloaders.com/ctml_experiments/bp_burning/bp_burning.html
http://www.frfrogspad.com/intballi.htm http://www.alliantpowder.com/getting_started/safety/storage_handling.aspx
these should answer most of the questions as for the way smokeless and black powder burn the are both self contained reactions set off by catalysts black powder is more reactive at atmospheric pressure than smokeless and smokeless requires the heat and pressure to liberate the oxygen for the reaction to be efficient
black powder is a low explosive smokeless is a propellent remember the flash for the old pictures 1 gram of blackpowder burns in about .15 seconds in open air puff same amount of 4895 about 1.5seconds try it but not on your bench ,dont want your wife blaming me for burning the house down
Nice links buy not really supportive of your first assertion. Both powders are propellants. Both powders deflagrate as opposed to "explode." Low explosives deflagrate at subsonic speeds, whereas high explosives detonate, producing a supersonic wave. Both powders will "explode" or burst a vessel if contained. Oddly enough, smokeless powder IS a true high explosive. Initiate it with a blasting cap or a primary like acetone peroxide and it'll detonate, uncontained.
I've never heard of using BP for flash photography. "Flashpowder" is a far cry from black powder, not even in the same ballpark, but at any rate comparing a slowburning rifle powder to black doesn't seem right.....IMO a more fair comparison would be to rate propagation of a fast smokeless like Clays or Bullseye instead of 4895.
BTW I did almost burn my buddy's house down 35yrs ago with homade BP long story concerning mfgr of wick material, rocket motors and loose blackpowder. The Good Lord looks out for fools sometimes.
It wasn't until 20yrs later I was introduced to flashpowder. Wicked stuff, NOT a propellant! Novelty or pyro only....
al